Open Chemistry Journal




ISSN: ― Volume ,
RESEARCH ARTICLE

Synthesis, Spectral and Thermo-Gravimetric Analysis of Novel Macromolecular Organo-Copper Surfactants



Anju Joram1, Rashmi Sharma1, Arun K. Sharma2, *
1 Department of Chemistry, S.P.C. Govt. College Ajmer-305001, Rajasthan, India
2 Department of Chemistry, Govt. P.G. College, Jhalawar-326001, Rajasthan, India

Abstract

Background:

The present paper highlights:

Synthesis of copper surfactants derived from edible oils i.e. Groundnut & Sesame and non-edible oils i.e. Neem & Karanj.

Methods:

Spectral studies (IR, NMR) have been carried out to understand the structural insight of the surfactants synthesized.

Results and Conclusion:

Thermogravimetric analysis of copper surfactants derived from Groundnut, Sesame, Neem & Karanj has been done to confirm the thermal decomposition/stability. Kinetic parameter i.e. activation energy and thermodynamic parameters i.e. Gibbs free energy, entropy and enthalpy were calculated by five different well-known equations namely Freeman Carroll, Coats - Redfern, Horowitz – Metzger, Broido, and Piloyan –Novikova.

Keywords: Copper surfactants, IR, NMR, ESR, TGA, Gibbs free energy.


Article Information


Identifiers and Pagination:

Year: 2018
Volume: 5
First Page: 145
Last Page: 157
Publisher Id: CHEM-5-145
DOI: 10.2174/1874842201805010145

Article History:

Received Date: 15/8/2018
Revision Received Date: 1/11/2018
Acceptance Date: 5/11/2018
Electronic publication date: 30/11/2018
Collection year: 2018

© 2018 Joram et al.

open-access license: This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 International Public License (CC-BY 4.0), a copy of which is available at: https://creativecommons.org/licenses/by/4.0/legalcode. This license permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.


* Address correspondence to this autor at the Department of Chemistry, Govt. P.G. College, Jhalawar-326001, Rajasthan, India; Tel: +919352669899; E-mail: sharmaarun423@gmail.com



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I am completely satisfied with the service I received from Bentham Science Publishers, right from the submission of our research paper in ‘Open Chemistry’ to its publication in the journal. The reviewers' and editor's comments were very helpful in improving the paper.

I take this opportunity to express my appreciation to the whole team of BSP!


Dr. Arun Kumar Sharma
Govt. P.G. College,
India


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