Synthesis, Spectral and Thermo-Gravimetric Analysis of Novel Macromolecular Organo-Copper Surfactants
Anju Joram1, Rashmi Sharma1, Arun K. Sharma2, *
1 Department of Chemistry, S.P.C. Govt. College Ajmer-305001, Rajasthan, India
2 Department of Chemistry, Govt. P.G. College, Jhalawar-326001, Rajasthan, India
Abstract
Background:
The present paper highlights:
Synthesis of copper surfactants derived from edible oils i.e. Groundnut & Sesame and non-edible oils i.e. Neem & Karanj.
Methods:
Spectral studies (IR, NMR) have been carried out to understand the structural insight of the surfactants synthesized.
Results and Conclusion:
Thermogravimetric analysis of copper surfactants derived from Groundnut, Sesame, Neem & Karanj has been done to confirm the thermal decomposition/stability. Kinetic parameter i.e. activation energy and thermodynamic parameters i.e. Gibbs free energy, entropy and enthalpy were calculated by five different well-known equations namely Freeman Carroll, Coats - Redfern, Horowitz – Metzger, Broido, and Piloyan –Novikova.
Keywords: Copper surfactants, IR, NMR, ESR, TGA, Gibbs free energy.
Article Information
Article History:
Received Date: 15/8/2018
Revision Received Date: 1/11/2018
Acceptance Date: 5/11/2018
Electronic publication date: 30/11/2018
Collection year: 2018
© 2018 Joram et al.
open-access license: This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 International Public License (CC-BY 4.0), a copy of which is available at:
https://creativecommons.org/licenses/by/4.0/legalcode. This license permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
* Address correspondence to this autor at the Department of Chemistry, Govt. P.G. College, Jhalawar-326001, Rajasthan, India; Tel: +919352669899; E-mail: sharmaarun423@gmail.com
Open Peer Review Details |
Manuscript submitted on 15-8-2018 |
Original Manuscript |
Synthesis, Spectral and Thermo-Gravimetric Analysis of Novel Macromolecular Organo-Copper Surfactants |