Table 5: Selected bond lengths (Å) and angles(°) for cyGdCu.
Bond lengths
|
|
|
|
Cu1-N1
|
1.916(5)
|
Cu2-N3
|
1.919(5)
|
Cu1-N2
|
1.912(5)
|
Cu2-N4
|
1.923(5)
|
Cu1-O2
|
1.898(5)
|
Cu2-O6
|
1.912(4)
|
Cu1-O4
|
1.911(5)
|
Cu2-O8
|
1.906(5)
|
Gd1-O1
|
2.554(5)
|
Gd2-O5
|
2.575(5)
|
Gd1-O2
|
2.332(4)
|
Gd2-O6
|
2.404(4)
|
Gd1-O3
|
2.635(5)
|
Gd2-O7
|
2.545(4)
|
Gd1-O4
|
2.335(5)
|
Gd2-O8
|
2.334(4)
|
Bond angles |
|
|
|
N1-Cu1-N2
|
87.1(2)
|
N3-Cu2-N4
|
87.2(2)
|
N1-Cu1-O2
|
94.8(2)
|
N3-Cu2-O6
|
95.2(2)
|
N1-Cu1-O4
|
169.1(2)
|
N3-Cu2-O8
|
177.7(2)
|
N2-Cu1-O2
|
173.4(2)
|
N4-Cu2-O6
|
177.5(2)
|
N2-Cu1-O4
|
95.6(2)
|
N4-Cu2-O8
|
93.6(2)
|
O2-Cu1-O4
|
83.69(19)
|
O6-Cu2-O8
|
83.99(18)
|
O1-Gd1-O2
|
63.05(16)
|
O5-Gd2-O6
|
61.45(14)
|
O1-Gd1-O3
|
157.54(15)
|
O5-Gd2-O7
|
154.91(15)
|
O1-Gd1-O4
|
128.69(15)
|
O5-Gd2-O8
|
125.72(15)
|
O2-Gd1-O3
|
123.89(16)
|
O6-Gd2-O7
|
126.00(14)
|
O2-Gd1-O4
|
65.98(17)
|
O6-Gd2-O8
|
65.24(15)
|
O3-Gd1-O4
|
60.61(15)
|
O7-Gd2-O8
|
63.06(15)
|