Table 7: Selected bond lengths (Å) and angles(°) for cyLuNi.
|
Bond lengths
|
|
|
|
|
Ni1-N1
|
1.848(15)
|
Ni2-N3
|
1.836(16)
|
|
Ni1-N2
|
1.857(14)
|
Ni2-N4
|
1.852(15)
|
|
Ni1-O2
|
1.888(14)
|
Ni2-O6
|
1.861(14)
|
|
Ni1-O4
|
1.814(14)
|
Ni2-O8
|
1.806(14)
|
|
Lu1-O1
|
2.477(15)
|
Lu2-O5
|
2.523(13)
|
|
Lu1-O2
|
2.287(13)
|
Lu2-O6
|
2.338(14)
|
|
Lu1-O3
|
2.451(12)
|
Lu2-O7
|
2.471(13)
|
|
Lu1-O4
|
2.302(13)
|
Lu2-O8
|
2.270(13)
|
| Bond angles |
|
|
|
|
N1-Ni1-N2
|
87.4(6)
|
N3-Ni2-N4
|
88.0(7)
|
|
N1-Ni1-O2
|
95.8(6)
|
N3-Ni2-O6
|
95.2(7)
|
|
N1-Ni1-O4
|
176.3(6)
|
N3-Ni2-O8
|
174.5(7)
|
|
N2-Ni1-O2
|
176.2(6)
|
N4-Ni2-O6
|
175.6(7)
|
|
N2-Ni1-O4
|
96.1(6)
|
N4-Ni2-O8
|
94.9(6)
|
|
O2-Ni1-O4
|
80.9(6)
|
O6-Ni2-O8
|
82.2(6)
|
|
O1-Lu1-O2
|
63.6(5)
|
O5-Lu2-O6
|
62.6(4)
|
|
O1-Lu1-O3
|
152.2(5)
|
O5-Lu2-O7
|
150.2(5)
|
|
O1-Lu1-O4
|
123.0(5)
|
O5-Lu2-O8
|
124.3(4)
|
|
O2-Lu1-O3
|
127.4(4)
|
O6-Lu2-O7
|
126.5(4)
|
|
O2-Lu1-O4
|
63.1(4)
|
O6-Lu2-O8
|
63.1(5)
|
|
O3-Lu1-O4
|
64.8(5)
|
O7-Lu2-O8
|
66.4(5)
|