Table 8: Selected bond lengths (Å) and angles(°) for cyLuCu.
|
Bond lengths
|
|
|
|
|
Cu1-N1
|
1.918(4)
|
Cu2-N3
|
1.914(4)
|
|
Cu1-N2
|
1.920(4)
|
Cu2-N4
|
1.913(4)
|
|
Cu1-O2
|
1.893(5)
|
Cu2-O6
|
1.914(4)
|
|
Cu1-O4
|
1.907(4)
|
Cu2-O8
|
1.917(5)
|
|
Cu1-O9
|
2.399(5)
|
Cu2-O18
|
2.361(4)
|
|
Lu1-O1
|
2.443(4)
|
Lu2-O5
|
2.676(4)
|
|
Lu1-O2
|
2.262(3)
|
Lu2-O6
|
2.225(4)
|
|
Lu1-O3
|
2.594(4)
|
Lu2-O7
|
2.465(4)
|
|
Lu1-O4
|
2.250(4)
|
Lu2-O8
|
2.259(3)
|
| Bond angles |
|
|
|
|
N1-Cu1-N2
|
87.89(18)
|
N3-Cu2-N4
|
86.94(19)
|
|
N1-Cu1-O2
|
94.84(18)
|
N3-Cu2-O6
|
95.87(17)
|
|
N1-Cu1-O4
|
175.80(19)
|
N3-Cu2-O8
|
178.04(17)
|
|
N2-Cu1-O2
|
173.37(16)
|
N4-Cu2-O6
|
169.68(17)
|
|
N2-Cu1-O4
|
95.98(17)
|
N4-Cu2-O8
|
94.78(17)
|
|
O2-Cu1-O4
|
81.14(16)
|
O6-Cu2-O8
|
82.28(16)
|
|
O1-Lu1-O2
|
65.29(14)
|
O5-Lu2-O6
|
61.31(13)
|
|
O1-Lu1-O3
|
154.02(13)
|
O5-Lu2-O7
|
155.82(13)
|
|
O1-Lu1-O4
|
131.01(12)
|
O5-Lu2-O8
|
124.37(13)
|
|
O2-Lu1-O3
|
125.85(13)
|
O6-Lu2-O7
|
133.25(12)
|
|
O2-Lu1-O4
|
66.43(14)
|
O6-Lu2-O8
|
68.39(15)
|
|
O3-Lu1-O4
|
62.01(12)
|
O7-Lu2-O8
|
64.86(14)
|