Table 9: Selected bond lengths (Å) and angles(°) for cyLuZn.
|
Bond lengths
|
|
|
|
|
Zn1-N1
|
2.017(10)
|
Zn2-N3
|
2.017(8)
|
|
Zn1-N2
|
2.054(9)
|
Zn2-N4
|
2.051(10)
|
|
Zn1-O2
|
2.027(9)
|
Zn2-O6
|
2.042(10)
|
|
Zn1-O4
|
2.015(9)
|
Zn2-O8
|
1.998(8)
|
|
Zn1-O9
|
1.996(9)
|
Zn2-O17
|
1.972(9)
|
|
Lu1-O1
|
2.539(9)
|
Lu2-O5
|
2.599(9)
|
|
Lu1-O2
|
2.265(9)
|
Lu2-O6
|
2.242(8)
|
|
Lu1-O3
|
2.626(9)
|
Lu2-O7
|
2.559(9)
|
|
Lu1-O4
|
2.253(9)
|
Lu2-O8
|
2.232(8)
|
| Bond angles |
|
|
|
|
N1-Zn1-N2
|
81.8(3)
|
N3-Zn2-N4
|
81.6(3)
|
|
N1-Zn1-O2
|
89.0(4)
|
N3-Zn2-O6
|
89.7(4)
|
|
N1-Zn1-O4
|
152.0(4)
|
N3-Zn2-O8
|
145.3(3)
|
|
N2-Zn1-O2
|
137.1(3)
|
N4-Zn2-O6
|
144.3(4)
|
|
N2-Zn1-O4
|
90.8(4)
|
N4-Zn2-O8
|
89.9(3)
|
|
O2-Zn1-O4
|
78.1(4)
|
O6-Zn2-O8
|
77.8(4)
|
|
O1-Lu1-O2
|
63.1(3)
|
O5-Lu2-O6
|
62.2(3)
|
|
O1-Lu1-O3
|
148.5(3)
|
O5-Lu2-O7
|
147.6(3)
|
|
O1-Lu1-O4
|
130.8(3)
|
O5-Lu2-O8
|
125.2(3)
|
|
O2-Lu1-O3
|
125.4(3)
|
O6-Lu2-O7
|
131.8(3)
|
|
O2-Lu1-O4
|
68.6(3)
|
O6-Lu2-O8
|
69.1(3)
|
|
O3-Lu1-O4
|
61.9(3)
|
O7-Lu2-O8
|
63.4(3)
|