Table 1: NMR Spectral Data for Compounds 2 and 3 in CDCl3

δH δC
Position 2 3 2 3
1 1.79 (1H, m) 1.46 (1H, m) 35.33 34.79
2.11(1H, m) 1.86 (1H, m)
2 2.46 (1H, dt J=5.7,15.0) 1.73 (1H, m) 34.34 27.43
2.70 (1H, dt J=12.9, 15.9) 1.69 (1H, m)
3 3.30(1H, dd, J=5.7, 11.5) 214.63 77.94
4 47.20 38.92
5 1.48 (1H, dd J=3.2, 14.5) 1.63(1H, dd, J=5.4, 12.0) 50.36 49.82
6 2.35 (1H, m) 2.39 (1H, m) 37.13 36.65
2.54 (1H, m) 2.41 (1H, m)
7 198.03 199.05
8 139.48 138.89
9 162.67 164.78
10 39.38 39.76
11 2.36 (1H, m) 2.35 (1H, m) 23.79 23.64
2.31 (1H, m)
12 1.79 (1H, m) 1.82 (1H, m) 30.08 30.12
13 44.92 44.95
14 47.76 47.75
15 1.34 (1H, m) 2.07 (1H, m) 31.83 31.97
1.97 (1H, m) 1.73 (1H, m)
16 2.09 (1H, m) 1.96 (1H, m) 28.64 28.76
1.69 (1H, m) 1.35 (1H, m)
17 2.16 (1H, m) 1.44 (1H, m) 48.93 48.92
18 0.69 (3H, s) 0.70 (3H, s) 15.86 15.80
19 1.34 (3H, s) 1.21 (3H, s) 17.87 18.36
20 1.43 (1H, m) 1.47 (1H, m) 36.17 36.22
21 0.94 d (3H, d, J=6.1) 0.97 (3H, d, J=5.7) 18.54 18.60
22 2.48 (1H, m) 1.58 (1H, m) 34.82 34.88
1.20 (1H, m)
23 2.25 (1H, m) 2.25 (1H, m) 25.58 25.62
2.12 (1H, m)
24 6.88 (1H, dd, J=8.4, 7.7) 6.76 (1H, t, J=7.0) 142.97 143.08
25 127.19 127.18
26 168.71 168.71
27 1.84 (3H, s) 1.82 (3H, s) 12.31 12.34
28 0.94 (3H, s) 0.93 (3H, s) 24.87 24.98
29 1.12 (3H, s) 1.00 (3H, s) 25.32 27.41
30 1.10 (3H, s) 0.88 (3H, s) 21.36 15.29
31 3.58 (3H, s) 3.71 (3H, s) 51.65 51.69